Removal of an Azo Dye Congo Red from Aqueous Solution by Electro Coagulation Associated with the In-Situ Adsorption Process

Authors

  • S. Mohan Department of Physics, Bangalore University, Bangalore, Karnataka, India
  • B. M. Nagabhushana Department of Chemistry, M.S. Ramaiah Institute of Technology, Bangalore, Karnataka, India
  • Chikkahanumantharayappa Department of Physics, Vivekananda Degree College, Bangalore, Karnataka, India
  • C. Shivakumara Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore, Karnataka, India

DOI:

https://doi.org/10.51983/ajsat-2021.10.1.2793

Keywords:

Electro Coagulation, PXRD, Congo Red, Copper Electrodes, Adsorption

Abstract

Effective removal of Congo red from the aqueous solution has been studied using the electro coagulation technique using copper wire as both cathode and anode. As the voltage increases from 0.0 V to 55.0 V DC voltage, the removal efficiency increases up to 98% with the time limit of 35 seconds at a normal pH value of 7.0 - 7.85. As the temperature increases from room temperature to 75 0C, the coagulation increases and even the number of pairs of electrodes plays an important role in coagulation. The obtained sludge is characterized to identify its composition.

References

D. Ogwoka Siringi, P. Home, Joseph S. Chacha, and Enno Koehn, “Is Electrocoagulation (EC) a solution to the treatment of wastewater and providing clean water for daily use,” Journal of Engineering and Applied Sciences, vol. 7, no. 2, pp. 197-204, February 2012.

A. I. Adeogun and R. B. Balakrishnan, “Removal of Basic Dye Bromophenol Blue from aqueous solution by Electrocoagulation using Al -Fe Electrodes: Kinetics, Equilibrium and Thermodynamics Studies,” Journal of Physical and Theoretical Chemistry, vol. 15, no. 1, pp. 87-103, Spring 2018.

M. S. Mahmoud, J. Y. Farah, and T. E. Farrag, “Enhanced removal of Methylene Blue by electrocoagulation using iron electrodes,” Egyptian Journal of Petroleum, vol. 22, pp. 211–216, 2013.

E. V. Vidya Vijay, M. Jerold, M. S. Ramya, S. Lakshman, and V. Sivasubramanian, “Electro coagulation using commercial grade aluminum electrode for the removal of crystal violet from aqueous solution,” Water Science and Technology, vol. 79, no. 4, pp. 597–606, 2019.

D. Sharma, “Treatment of Pulp and Paper Effluent by Electrocoagulation,” International Journal of Chem Tech Research, vol. 6, no. 1, pp. 860-870, March 2014.

X. Duan, Pan Wu, K. Pi, H. Zhang, D. Liu, and A. R. Gerson, “Application of Modified Electro coagulation for efficient color removal from Synthetic Methylene Blue Wastewater,” International Journal of Electrochemical Science, vol. 13, pp. 5575-5588, 2018.

N. Liu and Yunhai Wu, “Removal of methylene blue by electro coagulation: a study of the effect of operational parameters and mechanism,” Ionics Springer, vol. 25, no. 8, pp. 3953–3960, 2019.

J. Vidal, C. Espinoza, N. Contreras, and R. Salazar, “Elimination of industrial textile dye by Electro coagulation using iron electrodes,” Journal of Chil. Chem. Soc, vol. 62, no. 2, pp. 3519-3524, 2017.

M. A. Ahangarnokolaei, H. Ganjidoust, and B. Ayati, “Optimization of parameters of electrocoagulation/ flotation process for removal of Acid Red 14 with mesh stainless steel electrodes,” Journal of Water Reuse and Desalination, vol. 8, no. 2, pp. 278-292, 2018.

J. Castaneda-Diaz, T. Pavon-Silva, E. Gutierrez-Segure, and A. Colin-Cruz, “Electrocoagulation Adsorption to remove Anionic and Cationic Dyes from Aqueous Solution by PV-Energy,” Hindawi Journal of Chemistry, ID 5184590, 14 pages, 2017.

H. Zazoua, H. Afangaa, S. Akhouairia, H. Ouchtaka, A. Ait Addia, R. Ait Akboura, Ali Assabbanea, J. Doucha, A. Elmchaourib, J. Duplayc, A. Jadad, and M. Hamdania, “Treatment of textile industry wastewater by electrocoagulation coupled with electrochemical advanced oxidation process,” Journal of Water Process Engineering, vol. 28, pp.214-221, 2019.

S. Ali Sajjadi, A. Pakfetrat, and M. Irani, “Removal of Remazol Black B Dye by Electrocoagulation Process Coupled with Bentonite as an Aid Coagulant and Natural Adsorbent,” Iranian Journal of Health, Safety & Environment, vol. 5, no. 3, pp. 1058-1065, 2017.

K. Ulucan, H. Akif Kabuk, F. Ilhan, and U. Kurt, “Electrocoagulation Process Application in Bilge Water Treatment Using Response Surface Methodology,” International Journal of Electrochemical Science, vol. 9, pp. 2316 - 2326, 2014.

E. Bazrafshan, A. H. Mahavi, and M. A. Zazouli, “Textile Waste Water Treatment by Electrocoagulation Process Using Aluminium Electrodes,” Iranian Journal of Health Sciences, vol. 2, no. 1, pp. 16-29, 2014.

F. I. El-Hosiny, M. A. Abdel Khalek, K. A. Selim, and I. Osama, “Physicochemical study of dye removal using electro coagulation floatation process,” Physicochemical Problems of Mineral Processing, vol. 2, no. 54, pp. 321-333, 2018.

T. S. Anantha Singh and S. T. Ramesh, “New trends in Electro coagulation for the Removal of Dyes from Wastewater: A review,” Environmental Engineering Science, vol. 30, no. 7, pp. 333-349, 2013.

K. Vinothkumar, T. Sugumaran, and S. Venkateshwari, “Electrocoagulation coupled with adsorption for effective removal of eosin yellow and nigrosin dyes in aqueous solution,” Journal of Applied and Natural Science, vol. 11, no. 1, pp. 97-106, 2019.

M. Getaye, S. Hagos, Y. Alemu, Z. Tamene, and O. P. Yadav., “Removal of Malachite Green from Contaminated Water using Electro-Coagulation Technique,” Journal of Analytical & Pharmaceutical Research, vol. 6, no. 4, pp. 00184, 2017.

N. M. Abu Ghalwa, A. M. Saqer, and N. B. Farhat, “Removal of Reactive red 24 Dye by Clean Electro coagulation Process Using Iron and Aluminium Electrodes,” Journal of Chemical Engineering & Process Technology, vol. 7, no. 1, 2016.

M. S. I. Mozumder and M. A. Islam, “Development of Treatment Technology for Dye Containing Industrial Wastewater,” Journal of Scientific Research, vol. 2, no. 3, pp. 567-576, 2010.

A. Amour, B. Merzouk, Jean-pierre Leclerc, and Francois Lapicque, “Removal of reactive textile dye from aqueous solutions by electrocoagulation in a continuous cell,” Desalination and Water Treatment, vol. 57, no. 48-49, pp. 22764-22773, 2016.

Arega Y and Chavan RB, “Electrocoagulation Followed by Ion Exchange or Membrane Separation Techniques for Recycle of Textile Wastewater,” Advance Research in Textile Engineering, vol. 3, no. 2, pp. 1024, 2018.

R. Kaur and H. Kaur, “Electrochemical Degradation of Congo Red from Aqueous Solution: Role of Graphite Anode as Electrode Material,” Portugaliae Electrochimica Acta, vol. 34, no. 3, pp. 185-196, 2016.

O. D. Olukanni, A. A. Osuntoki, A. O. Awotula, D. C. Kalyani, G.O. Gbenle, and S. P. Govindwar, “Decolorization of Dyehouse Effluent and Biodegradation of Congo Red by Bacillus thuringiensis RUN1,” Journal of Microbiology and Biotechnology, vol. 23, no. 6, pp. 843–849, 2013.

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Published

16-02-2021

How to Cite

Mohan, S., Nagabhushana, B. M., Chikkahanumantharayappa, & Shivakumara, C. (2021). Removal of an Azo Dye Congo Red from Aqueous Solution by Electro Coagulation Associated with the In-Situ Adsorption Process . Asian Journal of Science and Applied Technology, 10(1), 5–12. https://doi.org/10.51983/ajsat-2021.10.1.2793