Preparation and Characterization of Activated Carbon from the Fruit of Cordia Sebestena as a Novel Adsorbent for Dye Removal

Authors

  • A. Geetha Centre for Environmental Research, Department of Chemistry, Kongu Engineering College, Perundurai, Erode, Tamilnadu, India
  • P. N. Palanisamy Centre for Environmental Research, Department of Chemistry, Kongu Engineering College, Perundurai, Erode, Tamilnadu, India

DOI:

https://doi.org/10.51983/ajsat-2017.6.2.986

Keywords:

Cordia Sebestena, Activated Carbon, Adsorption, H3PO4 impregnation, Dye removal

Abstract

Low cost adsorbents derived from wastes have demonstrated outstanding capabilities for the removal of dyes from wastewater. In the present study, fruit of Cordia Sebestena, a gardening plant material was used for the preparation of Activated Carbon. Activated carbons from the fruit of Cordia Sebestena were prepared by physical and chemical processes such as impregnation of raw material with Conc.H2SO4, KOH, ZnCl2, H3PO4 solution, direct pyrolysis, dolomite process, chemical activation with H2SO4 +H2O2 solution respectively followed by activation at 8000C.The physico- chemical characteristics such as moisture content , volatile matter, pH, conductivity, bulk density, specific gravity, porosity , methylene blue number, iodine number and SEM were investigated to study the adsorptive capacity. Among the prepared activated carbons, CSAC with H3PO4 solution followed by activation at 8000C possess high surface area and more porosity and was chosen as best adsorbent for the removal of dyes from textile industry effluent.

References

A. Ahmadpour and D. D. Do, "Carbon," vol. 34, no. 4, pp. 471, 1996.

R. Malik, D. S. Ramteke, and S. R. Wate, "Ind. J. Chem. Technol.," vol. 13, pp. 319-328, 2006.

S. Madhavakrishnan, K. Manickavasagam, R. Vasanthakumar, K. Rasappan, R. Mohanraj, and S. Pattabhi, "E Journal of Chemistry," vol. 6, no. 4, pp. 1109-1116, 2009.

P. Sivakumar and N. Palanisamy, "Advances in Applied Science Research," vol. 1, no. 1, pp. 58-65, 2010.

ISI, "Activated Carbon, Powdered and Granular – Methods of sampling and its tests," (Bureau of Indian Standards, New Delhi), IS 877 – 1989.

American Society for Testing Materials (ASTM), "Standard test method for Determination of Iodine Number of Activated Carbon D4607-94," ASTM, 1980.

S. Brunauer, P. H. Emmett, and E. Teller, "J. Am. Chem. Soc.," vol. 60, pp. 309-315, 1938.

S. Regnaraj, B. Arabindo, and V. Murugesan, "Ind. J. Chem. Technol.," vol. 6, pp. 1-4, 1999.

S. Karthikeyan, P. Sivakumar, and P. N. Palanisamy, "E-J. Chem.," vol. 5, pp. 409-426, 2008.

R. Malik, D. S. Ramteke, and S. R. Wate, "Ind. J. Chem. Technol.," vol. 13, pp. 319-328, 2006.

K. Mohanty, D. Das, and M. N. Biswas, "Adsorption," vol. 12, pp. 119–132, 2006.

R. Malik, D. S. Ramteke, and S. R. Wate, "Ind. J. Chem. Technol.," vol. 13, pp. 319-328, 2006.

L. Li, Effect of activated carbon surface chemistry and pore structure on the adsorption of trace organic contaminants from aqueous solution, Ph.D. Dissertation, North Carolina State University, 2002.

T. S. Anirudhan and K. A. Krishnan, "Removal of Cd2+ from aqueous solution by Steam-activated sulphurised carbon prepared from sugar-cane bagasse pith: Kinetics and equilibrium studies," Water SA, vol. 29, no. 2, pp. 147–156, 2003.

C. Karthika and M. Sekar, "Comparison studies of Adsorption Properties on Ni (II) Removal by Strong and Weak acid Cation-exchange Resins," Res. J. Chem. Sci., vol. 3, no. 3, pp. 65-69, 2013.

W. Shen, Z. Li, and Y. Liu, "Surface chemical functional groups modification of porous carbon," Recent Patents on Chemical Engineering, vol. 1, pp. 27-40, 2008.

M. Bansal, D. Singh, V. K. Garg, and R. Pawan, "Use of agricultural waste for the removal of Nickel ions from aqueous solutions: equilibrium and kinetic studies," Proceedings of International Conference on energy and Environment, March 19-21 2009.

R. M. Rao, M. Ahmedna, and W. E. Marshall, "Surface properties of granular activated carbons from agricultural by-products and their effects on raw sugar decolorization," Bioresource Technology, vol. 71, pp. 103-112, 2000.

M. Al-Mamun, M. Poostforush, S. A. Mukul, and M. A. Subhan, "Isotherm and Kinetics of As (III) Uptake from Aqueous Solution by Cinnamomum zeylanicum," Res. J. Chem. Sci., vol. 3, no. 3, pp. 34-41, 2013.

J. C. Garcia-Gil, S. B. Ceppi, M. I. Velasco, D. Polo, and N. Scnesi, "Long-term effects of amendment with municipal solid waste compost on the elemental and acidic functional group composition and Ph-buffer capacity of soil humic acid," Geoderma, vol. 121, pp. 135-142, 2004.

J. Guo and A. Lua, "Textural and chemical characterizations of activated carbon prepared from oil palm stone with H2SO4 and KOH impregnation," Microporous and Mesoporous Materials, vol. 32, pp. 111-117, 1999.

G. Socrates, Infrared Characteristic Group Frequencies, John Wiley & Sons, New York, 1994.

Downloads

Published

28-10-2017

How to Cite

Geetha, A., & Palanisamy, P. N. (2017). Preparation and Characterization of Activated Carbon from the Fruit of Cordia Sebestena as a Novel Adsorbent for Dye Removal. Asian Journal of Science and Applied Technology, 6(2), 39–45. https://doi.org/10.51983/ajsat-2017.6.2.986