Adsorption Kinetic and Isotherm Studies of Azure-A on Various Activated Carbons Derived from Low Cost Agricultural Wastes

Authors

  • Pandi Muthuraman Department of Chemistry, Yadava College, Thirupalai, Madurai, Tamil Nadu, India
  • Mayathevar Rajamani PG and Department of Chemistry, The Madura College, Madurai, Tamil Nadu, India
  • Arulanantham Xavier PG and Department of Chemistry, The Madura College, Madurai, Tamil Nadu, India

DOI:

https://doi.org/10.51983/tarce-2017.6.1.2233

Keywords:

Azure-A, Low Cost Carbon, Kinetics, Isotherm, SEM-Edax, Adsorption

Abstract

The present study narrates the eminent role of agricultural wastes as adsorbents viz., Sorghum Vulgare Carbon (SVC), Zea Mays Carbon (ZMC), Sorghum Vulgare Varity Carbon (SVVC), Ceiba Peutandra Carbon (CPC), Projobis Juliflora Carbon (PJC) for the removal of Azure-A (AA) dye from waste water. Experimental parameters such an effect of initialconcentration, contact time, dose, pH and particle size have been analyzed. The experimental results are there analyzed using Freundlich, Langmuir, Temkin, Redlich–Peterson and Dubinin–Radushkevich isotherm models. Multiple kinetic equations (first order, pseudo first order and pseudo second order) were applied to the adsorption kinetics of AA on various activated carbons. Surface morphology of the adsorbents before and after adsorption is studied by Scanning Electron Microscopy (SEM-Edax). FT-IR analyses revealed the presence of functional groups of dye on the adsorbents. It is inferred from the experimental result that the activated carbons (SVC, ZMC, SVVC, CPC and PJC) from agricultural wastes can be applied as an adsorbent in the removal of AA dye from waste water.

References

R.Han, D.Ding, Y.xu, W.Zou, Y.Wang, Y.Li and L.Zou, Bioresour, Technol, 99 (2008) 2938.

K.G.Bhattacharya and A.Sharma, J.Environ.Manage, 71 (2004) 217.

Y.Nakahino and K.Murakawa, Nippan Kogyo Kaishi, 98 (1982) 957.

F.O.Mixon, “Removal of Toxic Metals from water by Reverse Osmosis”, R and D Progress Report No, 889, Saline water, DOI, Washington DC, 1973.

E.Hindin G.H.Dunstan and R.J.Bannett, “Water Reclamation by Reverse Osmosis Bul”, 310, Tech, Ext, Service, Washington State Univ, Pullman.

M.J.Fishman and E.C.Mallory, J.Wat.poll.cont.Fed, 40 (1968) 67.

N.Nagesh and A.Krishnaiah, Indian J.Env,prot, 9 (1989) 304.

S.Suiha and Chandra , Water , Air, Soil Poll, 51 (1990) 271.

P.vasudevan and N.L.N.Sharma, J.Appl, Polym, Sci, 24 (1979) 1443.

A.Muzzarelli, G.Raith and O.Luberini, J.Chromat, 47 (1970) 314.

G.Lai and A.Goya, US.Govt, R and D Report, AD 648 (1996) 485.

T.C.Yanc and R.Zall, Ind.Eng.Chem.Res., 23 (1984) 168.

D.Tongzhou, S.Fanning, Zhuanli Shenging Gengkai Shuomingshu, 85 (1996) 102.

A.Muzzarelli, G.Raith,O.Lubertini, J.Chromat, 47 (1970) 314.

R.Tian,W.Zhao,Huangjing Kexve, 5 (1984) 136.

S.Hayastu and K.Ayoma,Nippan kagaku kaishi, 3 (1984) 439.

K.Kojima and S.Iwabucin, Kango Kagaku Kenji, Hokoku, 9 (1983) 49.

F.Helfferich, “Ion Exchange Resins”, 3rd Edn, Wiley, NewYork, 962.

J.Oakes and P.Gratton, J.Chem.Soc.Perkin Trans, 2 (1998) 2201.

K.Enmanji and T.Takahashi, Nippon Kagaku Kaishi, 7 (1990) 797.

M.Sankaranaryanan and R.Vijayavalli,”Studies on Electrochemical Reduction of Hexavalent Chromium in Plating Effluent” In: ‘Advances in Environmental Science’, 24.C.S.P.Iyer(Ed).Educ.Book publ.New Delhi.P.369 24. (1997).

C.Appel, M.Lena, J.Environ.Qual, 31 (2002) 581.

T.J.Sorg,M.Csandy and G.S.Logsdon,J.Am.Wat.Wks.Assoc, 70 (1978) 680.

J.W.Peterson, E.Allen, J.Scala,J.Wat.Poll.Cont.Fed,49 (1977) 2397.

Gargi Biswas and P.Bhattacharya, Indian, J.Environ.Prot, 33 (2013) 533.

G.Mair, Am.J.Publ.Hlth.Eng, 16 (1971) 24.

J.P.Bonsack, Ind,Eng,Chem, 9 (1970) 254.

Y.Dong, Y.Su, W.Chen, J.Peng, Chines, J.Chem, Eng, 19 (2011) 863.

P.Sharma, H.Kaur, Appl, Water.Sci., 1 (2011) 135.

T.Shanthi,S.Manonmani,Chem,Res,Engg Bull,13 (2009) 1.

S.Patil,S.Renukdas, N.Patel,Inter,J.Environ,Sci,1 (2011) 711.

N.Kannan,M.Meenakshisundaram,Fres,Environ,Bull, 10 (2001) 814.

C.Namasivayam, D.Prabha,M.Kumutha, Bioresour,Technol, 64 (1998) 77.

N.Kannan,M.Meenakshisundaram,Indian,J.Environ Prot, 22 (2002) 495.

R.Shokoohi,V.Vatanpoors,M.Zarrbi,A.Vatani,E.J.Chem, 7 (2010) 65.

P.Velmurugan,V.Rathinakumar,G.Dhinakaran,Inter,J.Environ,Sci, 1(2011) 1492.

H.U.Itodo,A.U.Itodo,J.Chem,Pharm,Res, 2 (2010) 673.

V.Lakdhe,K.Wankhede,T.Patil,R.Patil,Sci,Environ.Sanit, 6 (2011) 149.

E.Demirbas,M.Kobya,T.Sulak,Bioresour,Technol, 99 (2008) 5368.

A.Khan,S.SharmaI.Ali,Toxial,Environ Health,Sci, 3(2011) 286.

E.S.Abechi,E.Gimba,A.Uzairu,A.Kagbu,Arch,Appl,Sci,Res, 3 (2011) 154.

Y.Durusan,O.Tepe,Environ,Sci,Pollut,Res,Int 20 (2013) 431.

S.Chowdary,P.Das Saha,Environ,Sci,Pollut, ,Int 20 (2013) 1050.

K.Algidsawi,Aust,J.Basic&Appl,Sci, 5 (2011) 1397.

G.Revathi,S.Ramalingam,P.Subramaniam,A.Ganapathi,E.J.Chem, 8 (2011) 1536.

T.Ananthabaskaran,N.Bhadusha,E.J.Chem, 8 (2011) 1696.

G.O.El-Sayed,E.Moustafa,F.Mahrous,Int,J,Chem Tech,Res, 3 (2011) 1606.

M.Arulkumar,P.Sathiskumar,T.Palvannan,J.HazardMater, 186 (2011) 827.

A.Jafar Ahamed,V.Balakrishnan,S.Arivoli,Arch,Sci,Res, 3 (2011) 154.

A.EL-Maghraby,A.EL-Deep,Global Nest, J., 13 (2011) 90.

S.Nethaji,A.Sivasamy,Chemosphere, 82 (2011) 1367.

R.Venkatraman,K.Hema,,V.Nandhakumar,S.Arivoli,J.Chem,Pharm,R es,3(2011)637.

R.Venkatraman,K.Hema,,V.Nandhakumar,S.Arivoli,J.Chem,Pharm,R es,3(2011)670.

M.Nageswara Rao, Y.Hanumantha Rao,Chakrapani,Ch.Sures Babu,J.chem,Pharm,Res, 3 (2011) 363.

M.Elmorsi,J.Environ,Protect, 2(2011) 817.

O.Theivarasu,S.Mylsamy,N.Sivakumar,Res,J.Chem,Sci, 1 (2011) 38.

H.Hameed,M.Din,L.Ahamaed,J.Hazard Mater, 141 (2007) 819.

T.Robinson,B,Chandran,P.Nigam,Bioresour,Technol, 85 (2002)119.

H.Ayidana,G.Baysalb, Desalination, 196 (2006) 248.

W.Tan,L.Ahamed,H.Hameed,J.Hazard Mater, 154 (2008) 337.

W.Tan,L.Ahamed,H.Hameed, Desalination, 225 (2008) 13.

A.Ahamed,H.Hameed,N.Aziz, J.Hazard Mater, 141 (2007) 70.

S.Rajeswari,V.Subburam,Bioresour, Technol, 85 (2002) 205.

A.Ozer, G.Dursun, J.Hazard Mater, 146 (2007) 262.

S.Senthilkumar,P.Kalamani,K.Porkodi,R.Varadarajan, Bioresour, Technol, 97 (2006) 1618.

R.Han,Y.Wang,P.Han,J.Shi, J.Hazard Mater, B137 (2006) 550.

J.Raffea Baseri,N.Palanisamy,P.Sivakumar,Adv,Appl,Sci,Res, 3 (2012) 377.

V.Sivakumar, M.Asaithambi, P.sivakumar,Adv,Sci,3 (2012) 219.

K.Asiagwu,I.Owamah,O.Illoh,Adv, Appl, Sci, Res, 3 (2012) 2257.

A.Utayan,K.Gosh,Afr, J.Environ, Sci, Technol, 6 (2012) 146.

S.Patil, S.Renukadas, N.Patel, Inter,J.Environ ,Sci, 1(2011) 711.

A.Agalya, N.Palanisamy,P.Sivakumar, Appl,Sci, 3 (2012) 1220.

N.Renugadevi, R.Sangeetha,P.Lalitha, Arch,Appl,Sci,Res, 3 (2011) 492.

R.Lotfy, J.Misihairabgwi, M.Mulela Mutwa, Afr, J.Pure Appl,Chem, 6 (2012) 149.

P.Senthilkumar,S.Ramalingam,K.Sathiskumar,Korean,J.Chem,Eng, 28 (2011) 149.

C.Parvathi,T.Maruthuvanan,Indian,J.Sci,Technol, 3 (2010) 408.

R.Venckatesh, T.Amudha,S.Rajeswari,Inter,J.Engg,Sci,Technol, 2 (2010) 2040.

L.Wang, J.Zhang, R.Zhao,C.Li,Y.Li,Desalination, 254 (2010) 68.

K.Ramakrishnan, C.Namasivayam, J.Environ, Eng, Manage, 19 (2009) 173.

H.Trevino-Cordero, G.Juarez-Aguilar, I.Mendoza-Castillo, Ind,Corps, Prod, 42 (2013) 315.

X.Zhang, L.L.Ou,Water Sci, Technol, 67 (2013) 737.

P.Egwuonwu Dim,Aca, Res, Inter, 4 (2013) 330.

K.Mahadeo Doke, A.Chavan, R.Nalawade, M.Khan, J.Mater,Environ, Sci, 4 (2013) 374.

N.Thinakaran, P.Baskaralingam, M.Pulikesi, P.Pannerselvam, J.Hazard.mater, 151 (2008) 316.

S.Idris, J.Yisa, N.Muhammed, C.Chioma, Inter, J.Mod,Chem, 4 (2013) 90.

P.Gopalaswami, N.Sivakumar, S.Ponnusamy, V.Venkateswaran, J.Environ, Sci, Eng, 52 (2010) 367.

I.Owamah, S.Chukwuijindu, K.Asiagwu, Civil Environ, Res, 3 (2013) 36.

O.Alade, S.Amutha, O.Afolabi, J.Environ, Sci, Technol, 5 (2012) 192.

G.Patil and G.K.Nagada, Environ, Res, Eng, Manage, 1 (2013) 30.

M.EI Maghraby, Afr.J.Biotechnol, 12 (2013) 2215.

K.Nagda, S.Ghole, Iran, J.Environ, Health,Sci,Eng, 6 (2009) 195.

D.Shendkar, C.Torane, S.Mundhe, M.Lavate,Int, J.Pharm.Pharm.Sci., 5 (2013) 527.

M.Meenakshisundaram, N.Kannan, J.Regins, Indian, J.Environ, Protec, 31 (2011) 580.

O.Tunc, H.Tanci, Z.Aksu, J.Hazard Mater, 163 (2009) 187.

M.Husseien, A.A.Amer,A.EI-Maghraby,A.Tahaused, J.App,Sci, Res, 3 (2007) 1352.

A.Khaled, EL Nemr, A.EL Sikaily, O.Abdelwahab, Desalination, 238 (2009) 210.

L.Foletto,T.Weber, S.Paz,A.Mazutti, L.Meili,Water Sci, Technol, 67 (2013) 201.

M.Meenakshisundaram, K.Shahul Hameed, J.Chem.Pharm, Res, 4 (2012) 2070.

M.Meenakshisundaram, K.Shahul Hameed, J.Chem.Pharm, Res, 3 (2012) 242.

K.Masud Hossain, Indian, J.Environ, Prot, 33 (2013) 554.

N.Kannan, R.Pagutharivalan, , Indian, J.Environ, Prot, 33 (2013) 602.

Vaughan, W.F.Seo and Marshall Bioresourse, Technol, 78(2001)133.

Shikha Dubey, Uma, Lavanchawee Sujarittanonta & Yogesh Chandra Sharma, Desalination and Water Treatment, Taylor & Francis,Informa Ltd Registered Number: 1072954.

Mohd Azmier Ahmad∗, Rasyidah Alrozi, ScienceDirect Chemical Engineering Journal, April 2011.

M.Salleh, K.mahmoud, E.A.Al-Maamary, J.Adv, Sci, Eng, Res, 1 (2011) 554.

N.Kannan, R.Sivasubramani, Indian, J.Environ, Prot, 33 (2013) 602.

N.Kannan, A.Raj kumar, Fres, Environ, Bull, 11 (2002) 75.

N.Kannan, K.Karuppasamy, , Indian, J.Environ, Prot, 18 (1998) 683.

N.Kannan,A.Xavier, Toxic, Environ, Chem, 79 (2001) 95.

Y.Foo, H.Hameed, Chem, Eng, J, 8 (2010) 2.

W.Adamson,Physical Chemistry of Surface, Inter Science Publ,Inc, NewYork, p.777 (1960).

F.Freundlich, J.Phys.Chem, 57 (1906) 385.

R.Hall,C.Eagleton, A.Acrivos, T.Vermevlem, Ind, Eng,Chem., 5 (1966) 212.

J.Temkin, V.Pyzhev, A.Physiochim,URSS, 12 (1940) 217.

T.Shahwan, N.Erten, J.Radional Nucl.,Chem, Articles, 260 (2004) 43.

O.Redlich, L.Peterson, J.Phys.Chem, 63 (1959) 1024.

S.Ozcan, B.Erdem, A.Ozcan, Colloid Surf.A: Physicochem,Eng, Aspects, 266 (2005) 73.

N.Kannan, M.Meenakshisundaram, Dyes Pigments, 51 (2001) 25.

J.Weber, C.Morris, In: Eckenfelder, W.W.Editor, Advances in Water Pollution Research, Pergamon Press, Oxford, 1964.

H.Chen, J.Zhao, G.Dai, J.Hazard Mater, 186 (2011) 1320.

J.Raffia Baseri, N.Palanisamy, P.Sivakumar, Int, J.Chem,Res, 3 (2012) 36.

E.Forgacs, T.Cserhati, G.Oros, Environ, Int, 30 (2004) 953

A.Bandyopadhyay, S.Biswas, Indian, J.Environ, Protec, 18 (1998) 662.

K.Esumi, Y.Takeda, Y.Koide, Colloid Surf, A: Physicochem, Eng, Aspect, 135 (1998) 59.

A.Basar, J.Hazard.Mater, B135 (2006) 232.

V.Shrivastava, M.Hambarde, H.Kumar, Int, J.Green Herb, Chem, 1 (2012) 46.

K.Verma, K.Mishra, Global Nest, J., 12 (2010) 190.

H.Hameed, J.Hazard.Mater, 162 (2009) 939.

S.Arivoli, M,Hema, S.Parthasarathi,, J.Chem.Pharm, Res., 2 (2010) 626.

S.Cengiz, L.Cavas, Bioresour, Technol, 99 (2008) 2357.

M.Akhtar, S.Iqbalb, M.I.Bhanger, M.Zia-UI-Haq,M.Moazzam, Colloids and surface B: Bio interface., 69 (2009) 63.

S.Sumathi, S.Bhatia, T.Lee, Chem.,Eng., J.,162 (2010) 51.

K.Hameed, M.Noor, R.Afida, N.Mohad Asri, Desalination, 257 (2010) 1.

T.Maria, M.Sylwia, Water Res., 36 (2002) 4137.

M.Owlad, K.Aroua, W.Daud, Bioresour, Technol, 101 (2010) 5098.

B.Onundi, A.Mamun, F.Al Khatib, M.Ahmed, Int.J.Environ Sci., Tech, 7 (2010) 751.

N.Kannan, A.Rajkumar, Toxic, Environ, Chem., 84 (2003) 7.

A.Saeed, M.Iqbal,Water Res., 37 (2003) 3472.

D.Schimmel, C.Fagnani, B.Oliveira dos Santos, Braz,J.Chem, Eng., 27 (2010) 289.

D.Kavitha, C.Namasivayam, Chem, Eng, J., 139 (2008) 453.

K.Malik, J.Hazar.Mater., B113 (2004) 81.

S.Nethaji, A.Sivasamy, G.Thennarasu, S.Saravanan, J.Hazar.Mater. 181 (2010) 271.

X.Wu, N.Hui, S.Hui, K.Lee, W.Zhou, G.Son, Chem, Eng., J., 180 (2012) 91.

K.Malik, Dyes Pigments, 56 (2003) 239.

K.Hamadi, D.Chen, M.Farid, G.Lu, Chem, Eng, J., 84 (2001) 95.

M.Dogan, M.Alkan, Chemosphere, 50 (2003) 517.

Downloads

Published

05-05-2017

How to Cite

Muthuraman, P., Rajamani, M., & Xavier, A. (2017). Adsorption Kinetic and Isotherm Studies of Azure-A on Various Activated Carbons Derived from Low Cost Agricultural Wastes. The Asian Review of Civil Engineering, 6(1), 21–37. https://doi.org/10.51983/tarce-2017.6.1.2233